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Citronella would be the first natural product that comes to mind for controlling mosquitoes.

Offered by Mark.

Some Earth-friendly solutions to pest control are offered by Friedman & Sun Access Store and include using Sassafras, Citronella, Aloe, and Chrysanthemums.

Permaguard
Insecticides formulated from food grade diatomaceous earth, pyrethrins derived from chrysanthemums, and piperonyl butoxide derived from sassafras.
Earth Friendly Pest Control Solutions
SeaBrite's system is based on catching and holding pests using humane traps or sticky compounds. Their products are effective and ingenious. The Stickem Special and Green (copper added) is used on the trunks of fruit trees to prevent insect larvae from crawling up the tree and damaging the fruit.
Insect Repellents and Bite Treatment
Natrapel's insect repellent is made from 10% citronella in a non-greasy aloe vera and water base. It works well against mosquitoes, blackflies, biting midges, chiggers, gnats and fleas.
Natural Pet and Home Care
Natural Animal makes cruelty-free herbal and mineral insect repellents for people, pets and plants. Pyrethrum, a derivative of Chrysanthemums, is a highly toxic but biodegradable substance used for killing fleas and tics.

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